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| Title: | EXCITED STATE CHARGE TRANSFER AND DISSOCIATION OF Mg+-CH3I COMPLEX | |
| DOI No: | 10.1142/9789812701879_0012 | |
| Source: | CLUSTERS AND NANO-ASSEMBLIES (pp 89-95) | |
| Author(s): | FUMINORI MISAIZU
Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan ARI FURUYA Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan HIRONORI TSUNOYAMA Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan KOICHI OHNO Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan |
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| Abstract: | Photodissociation of Mg+-CH3I has been studied in the UV region using a reflectron time-of-flight mass spectrometer. Three bands were observed in a dissociation spectrum peaking at about 27200, 29600, and 38100 cm-1, which were assigned to the bands originating from 2P←2S transition of Mg+. Five kinds of ions, CH3+, Mg+, I+, CH3I+, and MgI+, were observed as fragment ions. Dissociation processes were discussed from the consideration of potential energy curves including charge transfer states obtained by CIS calculation. | |
| Full Text: | View full text in PDF format (369KB) | |
| TOC: | Back to Table of Contents | |
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