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Title:THE NATURE OF Sn (II) ADSORPTION FROM SOLUTIONS PROCEEDING WITH FORMATION OF NANOSTRUCTURED FILMS
DOI No:10.1142/9789812701947_0088
Source:PHYSICS, CHEMISTRY AND APPLICATION OF NANOSTRUCTURES (pp 394-397)
Author(s):O. V. REVA
Research Institute of Physico-Chemical Problems, Belarusian State University, Leningradskaya Str. 14, 220050 Minsk, Belarus

T. N. VOROBYOVA
Research Institute of Physico-Chemical Problems, Belarusian State University, Leningradskaya Str. 14, 220050 Minsk, Belarus

Abstract:It is shown that the adsorption of Sn(II) compounds proceeds by chemical mechanism when ion exchange with carboxyl groups is realized on the polyimide film from the acid and not aged SnCl2 solutions and by physical mechanism which includes colloidal particles sticking on the alkali silica glass from the acid and alkaline, freshly prepared and aged solutions. The adsorbed nanoparticles fulfill the function of the growth centers. It is determined that only chemical adsorption can provide the formation of island-type uniform monolayer film, which consists of the particles 5-10 nm in sizes at a quantity of 300-600 µm−2 and covers the dominating part of the substrates.
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